pimiПриборы и методы измеренийDevices and Methods of Measurements2220-95062414-0473BNTU10.21122/2220-9506-2017-8-3-214-221pimi-324Research ArticleСредства измеренийMeasuring instrumentsФЕРРОМАГНИТНЫЕ НАНОТРУБКИ В ПОРАХ ТРЕКОВЫХ МЕМБРАН ДЛЯ ЭЛЕМЕНТОВ ГИБКОЙ ЭЛЕКТРОНИКИFERROMAGNETIC NANOTUBES IN PORES OF TRACK MEMBRANES FOR THE FLEXIBLE ELECTRONIC ELEMENTSКанюковЕ. Ю.KaniukovE. Yu.

Address for correspondence: Kaniukov E.Yu. – Scientific and Practical Materials Research Center of NAS of Belarus, P. Brovka str., 19, Minsk 220072, Belarus   e-mail: Ka.egor@mail.ru

Ka.egor@mail.ruШумскаяЕ. Е.ShumskayaE. E.КутузовМ. Д.KutuzauM. D.

ул. П. Бровки, 19, г. Минск 220072

БоргековД. Б.BorgekovD. B.КенжинаИ. Е.KenzhinaI. E.КозловскийА. Л.KozlovskiyA. L.ЗдоровецМ. В.ZdorovetsM. V.Научно-практический центр НАН Беларуси по материаловедениюБеларусьScientific and Practical Materials Research Center of NAS of BelarusBelarusФилиал Института ядерной физики; Евразийский национальный университет им. Л.Н. ГумилеваКазахстанInstitute of Nuclear Physics; L.N. Gumilyov Eurasian National UniversityKazakhstan20172709201783214221Copyright © Канюков Е.Ю., Шумская Е.Е., Кутузов М.Д., Боргеков Д.Б., Кенжина И.Е., Козловский А.Л., Здоровец М.В., 20172017Канюков Е.Ю., Шумская Е.Е., Кутузов М.Д., Боргеков Д.Б., Кенжина И.Е., Козловский А.Л., Здоровец М.В.Kaniukov E.Y., Shumskaya E.E., Kutuzau M.D., Borgekov D.B., Kenzhina I.E., Kozlovskiy A.L., Zdorovets M.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://pimi.bntu.by/jour/article/view/324

В работе рассмотрены особенности шаблонного синтеза нанотрубок из ферромагнитных металлов (Fe, Co, Ni) в порах трековых мембран. Целью работы являлось изучение их основных структурных и магнитных параметров и демонстрация потенциала применения в элементах гибкой электроники.

При помощи электрохимического осаждения в порах полиэтилентерефталатовых трековых мембран сформированы ферромагнитные нанотрубки с диаметром 110 нм и аспектным соотношением 100. Методом сканирующей электронной микроскопии изучены морфологические особенности полученных наноструктур, методом энергодисперсионного анализа изучен элементный состав. С использованием рентгеноструктурного анализа установлены основные параметры кристаллической структуры: тип кристаллической решетки, параметр элементарной ячейки и средний размер кристаллитов. Методом вибрационной магнитометрии изучены магнитные свойства.

Показано, что вне зависимости от типа ферромагнитного металла при выбранных условиях синтеза нанотрубки имеют одинаковые характеристические размеры – длину, диаметр и толщину стенки. Полученные нанотрубки состоят соответственно из железа, из кобальта и из никеля и не содержат оксидных примесей. Нанотрубки имеют поликристаллическую структуру стенок с объемно-центрированной кубической (железные), гране-центрированной кубической (кобальтовые и никелевые) кристаллической решеткой. По основным магнитным параметрам нанотрубки соответствуют группе магнитомягких материалов. Также установлено наличие магнитной анизотропии, которая обусловлена особенностями кристаллической структуры и формой наноструктур.

На основании анализа особенностей структурных и магнитных характеристик ферромагнитных нанотрубок, синтезированных в порах трековых мембран, предложены базовые принципы их использования при конструировании элементов гибкой электроники: наноконденсаторов, датчиков направления магнитного поля и магнитных элементов памяти. 

In the paper the template synthesis of ferromagnetic (Fe, Co, Ni) nanotubes in the pores of track membranes were studied. The aim of this work was determination of nanotubes basic structural and magnetic parameters and demonstration of the possibility of application in the flexible electronics elements.

By electrochemical deposition, ferromagnetic nanotubes with a diameter of 110 nm and an aspect ratio of 100 were formed in the pores of polyethylene terephthalate track membranes. The morphology of the obtained nanostructures were studied by scanning electron microscopy, the elemental composition was determined by the energy-dispersion analysis. Using the X-ray structural analysis, the main parameters of the crystal structure were established: lattice type, lattice parameter and average crystallite size. The magnetic properties were studied by the method of vibrational magnetometry.

It was shown that in the selected conditions of synthesis without reference to the type of ferromagnetic metals nanotubes had the same dimensions – length, diameter and wall thickness. The produced nanotubes consisted of iron, cobalt and nickel, respectively without oxides impurities. Nanotubes had a polycrystalline structure of walls with a body-centered cubic (iron), face-centered cubic (cobalt and nickel) crystal lattice. According to the main magnetic parameters, nanotubes belonged to a group of soft magnetic materials. Also, the presence of magnetic anisotropy, which is caused by the features of crystalline structure and shape of the nanostructures.

Based on the analysis of structural and magnetic characteristics of ferromagnetic nanotubes which were synthesized in the pores of track membranes, were proposed the main principles of their using in the elements’ of flexible electronics constructing (magnetic field direction sensors and magnetic memory elements). 

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The authors declare that there are no conflicts of interest present.